Material Safety Data Sheet – Isopropyl alcohol MSDS

 

 

Chemical Product:

Product Name: Isopropyl alcohol

CAS number: 67-63-0

Synonyms: 2-propanol; sec-propyl alcohol; sec-propanol; dimethylcarbinol

Molecular formula: C3-H8-O

Chemical Formula: (CH3)2CHOH

Physical / Chemical Properties:

Physical state and appearance: Liquid
Odor: Rubbing alcohol. Pleasant. Odor resembling that of a mixture of ethanol and acetone.
Taste: Bitter (Slight)
Molecular Weight: 60.1 g/mole
Color: Clear, Colorless
Boiling Point: 82.5°C (180.5°F)
Melting Point: -88.5°C (-127.3°F)
Critical Temperature: 235°C (455°F)
Specific Gravity: 0.78505 (Water = 1)
Vapor Pressure: 4.4 kPa (@ 20°C)
Vapor Density: 2.07 (Air = 1)
Volatile by Volume: 100% @ 21 º C
Odor Threshold: 22 ppm (Sittig, 1991) 700 ppm for unadapted panelists (Verschuren, 1983).
Water/Oil Dist. Coeff.: The product is equally soluble in oil and water; log(oil/water) = 0.1
Dispersion Properties: See solubility in water, methanol, diethyl ether, n-octanol, acetone.
Solubility: Easily soluble in cold water, hot water, methanol, diethyl ether, n-octanol, acetone. Insoluble in salt solution. Soluble in benzene. Miscible with most organic solvents including alcohol, ethyl alcohol, chloroform.

Hazards Identification:

Potential Acute Health Effects: Hazardous in case of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant, sensitizer, permeator).
Potential Chronic Health Effects: Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH, 3 (Not classifiable for human.) by IARC. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Development toxin . The substance may be toxic to kidneys, liver, skin, central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage.

Fire and Explosion Hazard Data:

Flammability of the Product: Flammable.
Auto-Ignition Temperature: 399°C (750.2°F)
Flash Points: 12 º C (53.6°F)
Flammable Limits: LOWER: 2% UPPER: 12.7%
Products of Combustion: These products are carbon oxides (CO, CO2).

Fire Extinguishing Spray: Water spray, dry chemical, alcohol foam, or carbon dioxide. Water spray may be used to keep fire exposed containers cool, dilute spills and nonflammable mixtures, protect personnel attempting to stop leak and disperse vapors.

Explosion: Above flash point, vapor air mixtures are explosive within flammable limits noted above. Contact with strong oxidizers may cause fire or explosion. Vapors can flow along surfaces to distant ignition source and flash back. Sensitive to static discharge.

Fire Fighting Media and Instructions: Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam, water spray or fog.

Accidental Release Measures:

Small Spill: Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill: Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confined areas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

Potential Health Effects:

Inhalation: Inhalation of vapors irritates the respiratory tract. Exposure to high concentrations has anarcotic effect, producing symptoms of dizziness, drowsiness, headache, staggering, unconsciousness and possibly death.

Ingestion: Ingestion can cause drowsiness, unconsciousness, and death. Gastrointestinal pain,cramps, nausea, vomiting, and diarrhea may also result. The single lethal dose for a human adult = about 250 mls (8 ounces).

Skin Contact: May cause skin irritation with redness and pain. May be absorbed through the skin with possible systemic effects.

Eye Contact: Vapors cause eye irritation. Splashes caused severe irritation, possible corneal burns and eye damage.

First Aid Measures:

Inhalation: In case of Inhalation, remove to fresh air. In not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.

Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention.

Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Call a physician if irritation develops.

Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Personal Protective Equipment:

Skin Protection: Were impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Neoprene and nitrile rubber are recommended materials.

Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.

Handling and Storage:

Precautions: Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Avoid contact with eyes. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, acids.
Storage: Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).

Stability and Reactivity DataStability:

Stability: The product is stable.
Conditions of Instability: Heat, Ignition sources, incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Reacts violently with hydrogen + palladium combination, nitroform, oleum, COCl2, aluminum triisopropoxide, oxidants
Incompatible with acetaldehyde, chlorine, ethylene oxide, isocyanates, acids, alkaline earth, alkali metals, caustics, amines,
crotonaldehyde, phosgene, ammonia. Isopropyl alcohol reacts with metallic aluminum at high temperatures. Isopropyl alcohol attacks some plastics, rubber, and coatings. Vigorous reaction with sodium dichromate + sulfuric acid.
Special Remarks on Corrosivity: May attack some forms of plastic, rubber and coating

Ecological Information:

Ecotoxicity: Ecotoxicity in water (LC50): 100000 mg/l 96 hours [Fathead Minnow]. 64000 mg/l 96 hours [Fathead Minnow].
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.

Transport Information:

Shipping Name: Isopropanol

UN Number: UN1219

Hazard Class: 3

Packing Group: II

Labels: Flammable Liquid